MSDS2011

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

 

PRODUCT NAME:††††††† Blackberry & Brush Block For ORGANIC PRODUCTION

SYNONYMS:†††††††††††††††† 4b

 

MANUFACTURER:†††††† GREENERGY INC.

ADDRESS:††††††††††††††††††† POB 6669

††††††††††††††††††††††††††††††† ††††† BROOKINGS, OR. 97415

EMERGENCY PHONE:1-800-243-6925

CHEMTREC PHONE:†††† 1-800-424-9300

OTHER CALLS:††††††††††††† 1-541-619-2231

FAX PHONE:†††††††††††††††††† 1-360-735-0884

CHEMICAL NAME:†††††††† Water, Citric Acid

CHEMICAL FAMILY:††††

CHEMICAL FORMULA: CH3COOH + C6H8O7 + H2O

PRODUCT USE:†††††††††††† Blackberry & Brush Block

PREPARED BY:†††††††††††† JAMES NIELSEN, CONTACT

DATE PREPARED:†††††††† 11-02-04

SECTION 1 NOTES:†††††† None

††††††

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

†††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††

INGREDIENT: ††††††††††††††††††††††††† CAS NO††††††††††††††††† % Wt.†††† % VOL†††††††††††††††††† SARA 313 REPORTABLE

††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††† ††††††††††††††††††††††††††††††††††††††††††††† 5000 lbs. (99%)

Citric Acid†† 20%†††††††††††††††††† 77-92-9†††††††††††††††††† 20†††††††††††

Water††††††††† 80%††††††††††††††††††† 7732-18-5†††††††††††††† 82 †††††††††† 80

 

EXPOSURE LIMITS††††††††††††††††††††††††††††††† ppm††††††††††††††††† ††††††††††††††††††††mg/m3

†††††† OSHA PEL-TWA: ††††††††††††††††††††††††††† N/A

†††††† OSHA PEL STEL :

†††††† OSHA PEL CEILING:

††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††

†††††† ACGIH TLV-TWA:†††††††††††††††††††††††††† N/A

†††††† ACGIH TLV STEL:††††††

†††††† ACGIH TLV CEILING:

 

SECTION 2 NOTES:††† None

 

SECTION 3: HAZARDS IDENTIFICATION

†††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††††

ROUTES OF ENTRY:Skin and Eye Contact, Inhalation of Vapors, Ingestion

 

POTENTIAL HEALTH EFFECTS

†††††† EYES:Direct liquid contact with eyes can cause burning or severe irritation.

†††††††††††††

†††††† SKIN:†† Direct liquid contact with skin can cause irritation.

††††††††††††

†††††† INGESTION:Ingestion can irritate mouth, throat and other tissues of the respiratory and digestive tract.

†††††††††††††

†††††† INHALATION: Inhalation can irritate mouth, throat and other tissues of the respiratory tract.

†††††††††††††

ACUTE HEALTH HAZARDS:Direct liquid contact with skin or eyes can cause burns or severe irritation if not rinsed.

††††††

CHRONIC HEALTH HAZARDS:None known.

†††††

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:Preexisting skin or respiratory conditions might be aggravated upon contact or breathing of vapors.

 

 

CARCINOGENICITY:None Known

†††††† OSHA:†††††††††††††††††††††††††ACGIH:††††††††††††††††††††††††††† NTP:††††††††††††††††††††††††††IARC:†††††††††††† OTHER:

††††††††††††

SECTION 3 NOTES:None

†††††

 

SECTION 4:FIRST AID MEASURES

 

EYES: Rinse immediately with fresh water for 15 minutes.

††††††††††††

SKIN:Rinse immediately with fresh water for 15 minutes.

†††††

INGESTION:Remove victim to fresh air immediately

†††††

INHALATION:If chemical is swallowed,CALL PHYSICIAN OR POISON CONTROL CENTERfor most current information.Do Not Induce Vomiting unless instructed by Medical Professional.

††††††

NOTES TO PHYSICIANS OR FIRST AID PROVIDERS:None

††††††

SECTION 4 NOTES:None

††††††

SECTION 5: FIRE-FIGHTING MEASURES

 

FLAMMABLE LIMITS IN AIR, UPPER:None

††† (% BY VOLUME)††††††††††††††† LOWER:

 

FLASH POINT:None††††††††††† F:†††† C::

 

METHOD USED:

†††††††††

AUTOIGNITION TEMPERATURE:None†††††††††††††† F:†††† C:

 

NFPA HAZARD CLASSIFICATION

†††††† HEALTH: 1††††††††††††††††††††††††††††††† FLAMMABILITY: 0†††††††††††††††††††††††††† REACTIVITY:0†† †††††††††††††††† OTHER:

HMIS HAZARD CLASSIFICATION

†††††† HEALTH: 1†††††††††††††††††††††††††††††† FLAMMABILITY: 0††††††††††††††††††††††† REACTIVITY: 0

†††††† PROTECTION:Use rubber or neoprene gloves when handling liquid.

†††††††††††††

EXTINGUISHING MEDIA:N/A

††††††

SPECIAL FIRE FIGHTING PROCEDURES: None

††††††

UNUSUAL FIRE AND EXPLOSION HAZARDS: None

††††††

HAZARDOUS DECOMPOSITION PRODUCTS:None

††††††

SECTION 5 NOTES: None

††††††

SECTION 6: ACCIDENTAL RELEASE MEASURES

 

ACCIDENTAL RELEASE MEASURES: Releases of this material should be responded to by personnel with proper protective equipment (rubber or neoprene gloves, splash goggles or faceshields and aprons).Absorb spilled liquid with suitable absorbent material.Decontaminate the area thoroughly with water.Protect environmental exposures such as storm drains.

††††††

SECTION 6 NOTES:Dispose of all cleaned-up materials in accordance with all Federal, State and local disposal regulations.

 

SECTION 7:HANDLING AND STORAGE

 

HANDLING AND STORAGE:Avoid getting this product on you or in you.Wash hands after handling this product.Do not eat, drink or smoke while handling this product.

††††††

OTHER PRECAUTIONS:Use and store in well-ventilated area.

††††††

SECTION 7 NOTES: None

††††††

SECTION 8:EXPOSURE CONTROLS/PERSONAL PROTECTION

 

VENTILATION : Use and store in well-ventilated area.

††††††

RESPIRATORY PROTECTION:Generally not required.

††††††

EYE PROTECTION:To prevent eye contact, use splash goggles or a faceshield.

††††††

SKIN PROTECTION:Use rubber or neoprene gloves

††††††

OTHER PROTECTIVE CLOTHING OR EQUIPMENT:Wear clothing to prevent overall skin contact.

††††††

WORK HYGIENIC PRACTICES: Avoid getting this product on you or in you.Wash hands after handling this product.Do not eat, drink or smoke while handling this product.

 

EXPOSURE GUIDELINES:None

††††††

SECTION 8 NOTES:None

††††††

SECTION 9:PHYSICAL AND CHEMICAL PROPERTIES

 

APPEARANCE:Clear, colorless liquid

††††††

ODOR:light citric

††††††

PHYSICAL STATE:Liquid

††††††

pH AS SUPPLIED:†† 2.2

 

BOILING POINT:As water 212 F:†† 100 C:††

 

MELTING POINT:N/A†††††††† F:††† C:†††

 

FREEZING POINT As water32 F:0 C:

 

VAPOR PRESSURE (mmHg): As water760 @††† 68F:††† 23 C:††††

 

VAPOR DENSITY (AIR = 1): As water .624 @††† 68F:††† 23 C:

 

SPECIFIC GRAVITY (H2O = 1): As water@††† 68F:††† 23 C:†††††

EVAPORATION RATE: As water†††††††††††††††††††††††† BASIS (=1):†††

†††††††††

SECTION 9:PHYSICAL AND CHEMICAL PROPERTIES (conít)

 

SOLUBILITY IN WATER:Completely

††††††

PERCENT SOLIDS BY WEIGHT:20%

††††††

PERCENT VOLATILE:

6% BY WT/††† BY VOL @††††† 104 F:†††††† C:

VOLATILE ORGANIC COMPOUNDS (VOC):

††††††††††††† WITH WATER:††††††††††.526LBS/GAL

†††††† WITHOUT WATER:††††††††††††††††††† LBS/GAL

 

MOLECULAR WEIGHT:18.020As water

VISCOSITY: As water @††† 68F:††† 23 C:

 

SECTION 9 NOTES:None

††††††

SECTION 10: STABILITY AND REACTIVITY

 

STABLEYES††††††††††††††††††††††††††††††††††††††††††††††††† UNSTABLE

STABILITY:Stable under normal conditions of use and storage.

††††††

CONDITIONS TO AVOID (STABILITY):Heat.

††††††

INCOMPATIBILITY (MATERIAL TO AVOID):Concentrated citric acid is incompatible with many acids and solvents, strong caustics, oxidizers, carbonates, oxides and phosphates.

††††

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:May release irritating vapors especially at increased temperatures.

††††††

HAZARDOUS POLYMERIZATION:Will not occur.

††††††

CONDITIONS TO AVOID (POLYMERIZATION):N/A

††††††

SECTION 10 NOTES: None

††††††

SECTION 11:TOXICOLOGICAL INFORMATION

 

TOXICOLOGICAL INFORMATION:Citric Acid Monohydrate 99%: ipr-rat LD 50 375mg/kg

††††††††††††††††††††††††††††††††††††††††††††††† ††††††††††

††††††

SECTION 11 NOTES: None

††††††

SECTION 12:ECOLOGICAL INFORMATION

 

ECOLOGICAL INFORMATION:No specific data is available for this product.Refer to Section 6 for protection of environmental exposures.

††††††

SECTION 12 NOTES:None

SECTION 12:DISPOSALCONSIDERATIONS

 

WASTE DISPOSAL METHOD:Do not dispose by putting in a house or storm drain. Dispose of all cleaned-up materials in accordance with all Federal, State and local disposal regulations.

††††††

RCRA HAZARD CLASS:None known

 

SECTION 13:DISPOSALCONSIDERATIONS (conít)

 

SECTION 13 NOTES:None

††††††

SECTION 14:†† TRANSPORT INFORMATION

 

U.S. DEPARTMENT OF TRANSPORTATION

†††††† PROPER SHIPPING NAME:†††††††††† None known

†††††† HAZARD CLASS: †††††††††† ††††††††††††††† None known

†††††† ID NUMBER: ††††††††††††††††††††††††††††††††††† None known

†††††† PACKING GROUP: ††††††††††††††††††††††††† None known

†††††† LABEL STATEMENT:As required per OSHA Hazard Communication Standard 29 CFR 1910.1200

WATER TRANSPORTATION

†††††† PROPER SHIPPING NAME: ††††††††††† None known

†††† ††HAZARD CLASS: †††††††††††††††††††††††††† None known

†††††† ID NUMBER †††††††††††††††††††††††††††††††††††† None known

†††††† PACKING GROUP †††††††††††††††††††††††††† None known

†††††† LABEL STATEMENTS: As required per OSHA Hazard Communication Standard 29 CFR 1910.1200

AIR TRANSPORTATION

†††††† PROPER SHIPPING NAME: ††††††††††† None known

†††††† HAZARD CLASS: †††††††††††††††††††††††††† None known

†††††† ID NUMBER††† ††††††††††††††††††††††††††††††††† None known

†††††† PACKING GROUP †††††††††††††††††††††††††† None known

†††††† LABEL STATEMENTS: As required per OSHA Hazard Communication Standard 29 CFR 1910.1200

OTHER AGENCIES:None known

††††††

SECTION 14 NOTES:None

††††††

SECTION 15: REGULATORY INFORMATION

 

U.S. FEDERAL REGULATIONS:

†††††† TSCA (TOXIC SUBSTANCE CONTROL ACT):

†††††† CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT):

†††††† 311/312 HAZARD CATEGORIES:

313 REPORTABLE INGREDIENTS:Citric Acid

STATE REGULATIONS: None known††††††

INTERNATIONAL REGULATIONS: None known

SECTION 15 NOTES:None

††††††

SECTION 16: OTHER INFORMATION

 

OTHER INFORMATION: None

††††††

PREPARATION INFORMATION:

††††††

DISCLAIMER:The information contained herein is based on the data available to Greenergy and is believed to be correct.However, Greenergy makes no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.Greenergy assumes no responsibility for injury from the use of this product described herein.